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Hydrazine is an inorganic compound with the chemical formula N2H4. It is a simple pnictogen hydride, and is a Colourless and flammable liquid with an ammonia-like odor.

Hydrazine is highly toxic and dangerously unstable unless handled in solution as e.g., hydrazine hydrate (NH2NH2 · xH2O).

As of 2015, the world hydrazine hydrate market amounted to $350 million.[8] Hydrazine is mainly used as a foaming agent in preparing polymer foams, but applications also include its uses as a precursor to polymerization catalysts, pharmaceuticals, and agrochemicals.

About two million tons of hydrazine hydrate were used in foam blowing agents in 2015.

Additionally, hydrazine is used in various rocket fuels and to prepare the gas precursors used in air bags. Hydrazine is used within both nuclear and conventional electrical power plant steam cycles as an oxygen scavenger to control concentrations of dissolved oxygen in an effort to reduce corrosion.[9]

Hydrazines refer to a class of organic substances derived by replacing one or more hydrogen atoms in hydrazine by an organic group.[10]

Systematic IUPAC name
Other names
ECHA InfoCard100.005.560[79]
EC Number206-114-9
RTECS numberMU7175000
UN number2029
Molar mass32.0452 g·mol
AppearanceColorless, fuming, oily liquid[1]
Density1.021 g·cm
Melting point2 °C; 35 °F; 275 K
Boiling point114 °C; 237 °F; 387 K
log P0.67
Vapor pressure1 kP (at 30.7 °C)
Acidity(pK)8.10 (NH)[4]
Conjugate acidHydrazinium
1.46044 (at 22 °C)
Viscosity0.876 cP
Triangular pyramidal at N
1.85 D[5]
121.52 J·K·mol
50.63 kJ·mol
Safety data sheetICSC 0281[85]
GHS pictograms
GHS signal wordDANGER
,, ,, ,,,
,, ,,,
NFPA 704
Flash point52 °C (126 °F; 325 K)
24 to 270 °C (75 to 518 °F; 297 to 543 K)
Explosive limits1.8–99.99%
Lethal dose or concentration (LD, LC):
59–60 mg/kg (oral in rats, mice)[6]
260 ppm (rat, 4 hr)630 ppm (rat, 1 hr)570 ppm (rat, 4 hr)252 ppm (mouse, 4 hr)[7]
US health exposure limits (NIOSH):
TWA 1 ppm (1.3 mg/m) [skin][1]
Ca C 0.03 ppm (0.04 mg/m) [2-hour][1]
Ca [50 ppm][1]
Related compounds
tetrafluorohydrazinehydrogen peroxidediphosphanediphosphorus tetraiodide
organic hydrazines
Infobox references


Gas producers and propellants

The majority use of hydrazine is as a precursor to blowing agents. Specific compounds include azodicarbonamide and azobisisobutyronitrile, which produce 100–200 mL of gas per gram of precursor. In a related application, sodium azide, the gas-forming agent in air bags, is produced from hydrazine by reaction with sodium nitrite.[10]

Hydrazine is also used as a propellant onboard space vehicles, such as the NASA Dawn probe to Ceres and Vesta, and to both reduce the concentration of dissolved oxygen in and control pH of water used in large industrial boilers. The F-16 fighter jet, NASA Space Shuttle, and U-2 spy plane use hydrazine to fuel their emergency power units.[11]

Precursor to pesticides and pharmaceuticals

Fluconazole, synthesized using hydrazine, is an antifungal medication.

Fluconazole, synthesized using hydrazine, is an antifungal medication.

Hydrazine is a precursor to several pharmaceuticals and pesticides.

Often these applications involve conversion of hydrazine to heterocyclic rings such as pyrazoles and pyridazines. Examples of commercialized bioactive hydrazine derivatives include cefazolin, rizatriptan, anastrozole, fluconazole, metazachlor, metamitron, metribuzin, paclobutrazol, diclobutrazole, propiconazole, hydrazine sulfate,[12] diimide, triadimefon,[10] and dibenzoylhydrazine.

Hydrazine compounds can be effective as active ingredients in admixture with or in combination with other agricultural chemicals such as insecticides, miticides, nematicides, fungicides, antiviral agents, attractants, herbicides or plant growth regulators.[13]

Small-scale, niche, and research

The Italian catalyst manufacturer Acta (chemical company) has proposed using hydrazine as an alternative to hydrogen in fuel cells. The chief benefit of using hydrazine is that it can produce over 200 mW/cm2 more than a similar hydrogen cell without the need to use expensive platinum catalysts.[14] As the fuel is liquid at room temperature, it can be handled and stored more easily than hydrogen. By storing the hydrazine in a tank full of a double-bonded carbon-oxygen carbonyl, the fuel reacts and forms a safe solid called hydrazone. By then flushing the tank with warm water, the liquid hydrazine hydrate is released. Hydrazine has a higher electromotive force of 1.56 V compared to 1.23 V for hydrogen. Hydrazine breaks down in the cell to form nitrogen and hydrogen which bonds with oxygen, releasing water.[14] Hydrazine was used in fuel cells manufactured by Allis-Chalmers Corp., including some that provided electric power in space satellites in the 1960s.

A mixture of 63% hydrazine, 32% hydrazine nitrate and 5% water is a standard propellant for experimental bulk-loaded liquid propellant artillery. The propellant mixture above is one of the most predictable and stable, with a flat pressure profile during firing. Misfires are usually caused by inadequate ignition. The movement of the shell after a misignition causes a large bubble with a larger ignition surface area, and the greater rate of gas production causes very high pressure, sometimes including catastrophic tube failures (i.e. explosions).[15] From January–June 1991, the U.S. Army Research Laboratory conducted a review of early bulk-loaded liquid propellant gun programs for possible relevance to the electrothermal chemical propulsion program.[15]

The United States Air Force (USAF) regularly uses H-70, a 70% hydrazine 30% water mixture, in operations employing the General Dynamics F-16 “Fighting Falcon” fighter aircraft and the Lockheed U-2 “Dragon Lady” reconnaissance aircraft. The single jet engine F-16 utilizes hydrazine to power its Emergency Power Unit (EPU), which provides emergency electrical and hydraulic power in the event of an engine flame out. The EPU activates automatically, or manually by pilot control, in the event of loss of hydraulic pressure or electrical power in order to provide emergency flight controls. The single jet engine U-2 utilizes hydrazine to power its Emergency Starting System (ESS), which provides a highly reliable method to restart the engine in flight in the event of a stall.[16]

Rocket fuel

Anhydrous (pure, not in solution) hydrazine being loaded into the MESSENGER

Anhydrous (pure, not in solution) hydrazine being loaded into the MESSENGER

Hydrazine was first used as a component in rocket fuels during World War II. A 30% mix by weight with 57% methanol (named M-Stoff in the German Luftwaffe) and 13% water was called C-Stoff by the Germans.[17] The mixture was used to power the Messerschmitt Me 163B rocket-powered fighter plane. Hydrazine was also used as a propellant with the German high test peroxide T-Stoff oxidizer. Unmixed hydrazine was referred to as B-Stoff by the Germans, a designation also used later for the ethanol/water fuel for the V-2 missile.

Hydrazine is used as a low-power monopropellant for the maneuvering thrusters of spacecraft, and was used to power the Space Shuttle's auxiliary power units (APUs). In addition, monopropellant hydrazine-fueled rocket engines are often used in terminal descent of spacecraft. Such engines were used on the Viking program landers in the 1970s as well as the Phoenix lander and Curiosity rover which landed on Mars in May 2008 and August 2012, respectively.

In all hydrazine monopropellant engines, the hydrazine is passed over a catalyst such as iridium metal supported by high-surface-area alumina (aluminium oxide), which causes it to decompose into ammonia, nitrogen gas, and hydrogen gas according to the following reactions:[18]

→ +→ +
  • → +

The first two reactions are extremely exothermic (the catalyst chamber can reach 800 °C in a matter of milliseconds,[19]) and they produce large volumes of hot gas from a small volume of liquid,[20] making hydrazine a fairly efficient thruster propellant with a vacuum specific impulse of about 220 seconds.[21] Reaction 3 is endothermic and so reduces the temperature of the products, but also produces a greater number of molecules. The catalyst structure affects the proportion of the NH3 that is dissociated in Reaction 3; a higher temperature is desirable for rocket thrusters, while more molecules are desirable when the reactions are intended to produce greater quantities of gas.

Other variants of hydrazine that are used as rocket fuel are monomethylhydrazine, (CH3)NH(NH2) (also known as MMH), and unsymmetrical dimethylhydrazine, (CH3)2N(NH2) (also known as UDMH). These derivatives are used in two-component rocket fuels, often together with dinitrogen tetroxide, N2O4. These reactions are extremely exothermic, and the burning is also hypergolic (it starts burning without any external ignition).[22]

There are ongoing efforts in the aerospace industry to replace hydrazine and other highly toxic substances.

Promising alternatives include hydroxylammonium nitrate, 2-dimethylaminoethylazide (DMAZ)[23] and energetic ionic liquids.[24]

Occupational hazards

Health effects

Potential routes of hydrazine exposure include dermal, ocular, inhalation and ingestion.[25]

Hydrazine exposure can cause skin irritation/contact dermatitis and burning, irritation to the eyes/nose/throat, nausea/vomiting, shortness of breath, pulmonary edema, headache, dizziness, central nervous system depression, lethargy, temporary blindness, seizures and coma.

Exposure can also cause organ damage to the liver, kidneys and central nervous system.[25][26] Hydrazine is documented as a strong skin sensitizer with potential for cross-sensitization to hydrazine derivatives following initial exposure.[27] In addition to occupational uses reviewed above, exposure to hydrazine is also possible in small amounts from tobacco smoke.[26]

The official U.S. guidance on hydrazine as a carcinogen is mixed but generally there is recognition of potential cancer-causing effects.

The National Institute for Occupational Safety and Health (NIOSH) lists it as a “potential occupational carcinogen”. The National Toxicology Program (NTP) finds it is "reasonably anticipated to be a human carcinogen". The American Conference of Governmental Industrial Hygienists (ACGIH) grades hydrazine as "A3—confirmed animal carcinogen with unknown relevance to humans". The U.S. Environmental Protection Agency (EPA) grades it as "B2—a probable human carcinogen based on animal study evidence".[28]

The International Agency for Research on Cancer (IARC) rates hydrazine as "2A—probably carcinogenic to humans" with a positive association observed between hydrazine exposure and lung cancer.[29] Based on cohort and cross-sectional studies of occupational hydrazine exposure, a committee from the National Academies of Sciences, Engineering and Medicine concluded that there is suggestive evidence of an association between hydrazine exposure and lung cancer, with insufficient evidence of association with cancer at other sites.[30] The European Commission’s Scientific Committee on Occupational Exposure Limits (SCOEL) places hydrazine in carcinogen “group B—a genotoxic carcinogen”. The genotoxic mechanism the committee cited references hydrazine’s reaction with endogenous formaldehyde and formation of a DNA-methylating agent.[31]

In the event of a hydrazine exposure-related emergency, NIOSH recommends removing contaminated clothing immediately, washing skin with soap and water, and for eye exposure removing contact lenses and flushing eyes with water for at least 15 minutes. NIOSH also recommends anyone with potential hydrazine exposure to seek medical attention as soon as possible.[25] There are no specific post-exposure laboratory or medical imaging recommendations, and the medical work-up may depend on the type and severity of symptoms. The World Health Organization (WHO) recommends potential exposures be treated symptomatically with special attention given to potential lung and liver damage. Past cases of hydrazine exposure have documented success with Pyridoxine (Vitamin B6) treatment.[27]

Occupational exposure limits

  • NIOSH Recommended Exposure Limit (REL): 0.03 ppm (0.04 mg/m3) 2-hour ceiling[28]

  • OSHA Permissible Exposure Limit (PEL): 1 ppm (1.3 mg/m3) 8-hour Time Weighted Average[28]

  • ACGIH Threshold Limit Value (TLV): 0.01 ppm (0.013 mg/m3) 8-hour Time Weighted Average[28]

The odor threshold for hydrazine is 3.7 ppm, thus if a worker is able to smell an ammonia-like odor then they are likely over the exposure limit.

However, this odor threshold varies greatly and should not be used to determine potentially hazardous exposures.[32]

For aerospace personnel, the USAF uses an emergency exposure guideline, developed by the National Academy of Science Committee on Toxicology, which is utilized for non-routine exposures of the general public and is called the Short-Term Public Emergency Exposure Guideline (SPEGL). The SPEGL, which does not apply to occupational exposures, is defined as the acceptable peak concentration for unpredicted, single, short-term emergency exposures of the general public and represents rare exposures in a worker’s lifetime. For hydrazine the 1-hour SPEGL is 2 ppm, with a 24-hour SPEGL of 0.08 ppm.[33]

Handling and medical surveillance

A complete surveillance program for hydrazine should include systematic analysis of biologic monitoring, medical screening and morbidity/mortality information.

The CDC recommends surveillance summaries and education be provided for supervisors and workers. Pre-placement and periodic medical screening should be conducted with specific focus on potential effects of hydrazine upon functioning of the eyes, skin, liver, kidneys, hematopoietic, nervous and respiratory systems.[25]

Common controls used for hydrazine include process enclosure, local exhaust ventilation and personal protective equipment (PPE).[25] Guidelines for hydrazine PPE include non-permeable gloves and clothing, indirect-vent splash resistant goggles, face shield and in some cases a respirator.[32] The use of respirators for the handling of hydrazine should be the last resort as a method of controlling worker exposure. In cases where respirators are needed, proper respirator selection and a complete respiratory protection program consistent with OSHA guidelines should be implemented.[25]

For USAF personnel, Air Force Occupational Safety and Health (AFOSH) Standard 48-8, Attachment 8 reviews the considerations for occupational exposure to hydrazine in missile, aircraft and spacecraft systems. Specific guidance for exposure response includes mandatory emergency shower and eyewash stations and a process for decontaminating protective clothing. The guidance also assigns responsibilities and requirements for proper PPE, employee training, medical surveillance and emergency response.[33] USAF bases requiring the use of hydrazine generally have specific base regulations governing local requirements for safe hydrazine use and emergency response.

Molecular structure

Each H2N−N subunit is pyramidal.

The N−N single bond distance is 1.45 Å (145 pm), and the molecule adopts a gauche conformation.[34] The rotational barrier is twice that of ethane. These structural properties resemble those of gaseous hydrogen peroxide, which adopts a "skewed" anticlinal conformation, and also experiences a strong rotational barrier.

Synthesis and production

Diverse routes have been developed.[10] The key step is the creation of the nitrogen–nitrogen single bond.

The many routes can be divided into those that use chlorine oxidants (and generate salt) and those that do not.

Oxidation of ammonia via oxaziridines from peroxide

Hydrazine can be synthesized from ammonia and hydrogen peroxide in the Peroxide process (sometimes called Pechiney-Ugine-Kuhlmann process, the Atofina–PCUK cycle, or ketazine process).[10] The net reaction follows:[35]

In this route, the ketone and ammonia first condense to give the imine, which is oxidised by hydrogen peroxide to the oxaziridine, a three-membered ring containing carbon, oxygen, and nitrogen. Next, the oxaziridine gives the hydrazone by treatment with ammonia, which process creates the nitrogen-nitrogen single bond. This hydrazone condenses with one more equivalent of ketone.

The resulting azine is hydrolyzed to give hydrazine and regenerate the ketone, methyl ethyl ketone:

Unlike most other processes, this approach does not produce a salt as a by-product.[36]

Chlorine-based oxidations

In the Olin Raschig process, chlorine-based oxidants oxidize ammonia without the presence of a ketone. In the peroxide process, hydrogen peroxide oxidizes ammonia in the presence of a ketone.

Hydrazine is produced in the Olin-Raschig process from sodium hypochlorite (the active ingredient in many bleaches) and ammonia, a process announced in 1907. This method relies on the reaction of chloramine with ammonia to create the nitrogen–nitrogen single bond as well as a hydrogen chloride byproduct:[12]

Related to the Raschig process, urea can be oxidized instead of ammonia. Again sodium hypochlorite serves as the oxidant. The net reaction is shown:[37]

The process generates significant byproducts and is mainly practised in Asia.[10]

The Bayer Ketazine Process is the predecessor to the peroxide process. It employs sodium hypochlorite as oxidant instead of hydrogen peroxide. Like all hypochlorite-based routes, this method produces an equivalent of salt for each equivalent of hydrazine.[10]


Acid-base behavior

Hydrazine forms a monohydrate that is more dense (1.032 g/cm3) than the anhydrous material. Hydrazine has basic (alkali) chemical properties comparable to those of ammonia. It is difficult to diprotonate:[38]

with the values:[39]

Redox reactions

The heat of combustion of hydrazine in oxygen (air) is 1.941 × 107 J/kg (8345 BTU/lb).[40]

Hydrazine is a convenient reductant because the by-products are typically nitrogen gas and water.

Thus, it is used as an antioxidant, an oxygen scavenger, and a corrosion inhibitor in water boilers and heating systems. It is also used to reduce metal salts and oxides to the pure metals in electroless nickel plating and plutonium extraction from nuclear reactor waste. Some color photographic processes also use a weak solution of hydrazine as a stabilizing wash, as it scavenges dye coupler and unreacted silver halides. Hydrazine is the most common and effective reducing agent used to convert graphene oxide (GO) to reduced graphene oxide (rGO) via hydrothermal treatment.[41]

Hydrazinium salts

Hydrazine can be monoprotonated to form various solid salts of the hydrazinium cation (N2H5+) by treatment with mineral acids. A common salt is hydrazinium sulfate, [N2H5]HSO4, also called hydrazine sulfate.[42] Hydrazine sulfate was investigated as a treatment of cancer-induced cachexia, but proved ineffective.[43]

Double protonation gives the hydrazinium dication (H3NNH32+), of which various salts are known.[44]

Organic chemistry

Hydrazines are part of many organic syntheses, often those of practical significance in pharmaceuticals (see applications section), as well as in textile dyes and in photography.[10]

Hydrazine is used in the Wolff-Kishner reduction, a reaction that transforms the carbonyl group of a ketone into a methylene bridge (or an aldehyde into a methyl group) via a hydrazone intermediate. The production of the highly stable dinitrogen from the hydrazine derivative helps to drive the reaction.

Being bifunctional, with two amines, hydrazine is a key building block for the preparation of many heterocyclic compounds via condensation with a range of difunctional electrophiles. With 2,4-pentanedione, it condenses to give the 3,5-dimethylpyrazole.[45] In the Einhorn-Brunner reaction hydrazines react with imides to give triazoles.

Being a good nucleophile, N2H4 can attack sulfonyl halides and acyl halides.[46] The tosylhydrazine also forms hydrazones upon treatment with carbonyls.

Hydrazine is used to cleave N-alkylated phthalimide derivatives. This scission reaction allows phthalimide anion to be used as amine precursor in the Gabriel synthesis.[47]

Hydrazone formation

Illustrative of the condensation of hydrazine with a simple carbonyl is its reaction with propanone to give the diisopropylidene hydrazine (acetone azine).

The latter reacts further with hydrazine to yield the hydrazone:[48]

The propanone azine is an intermediate in the Atofina-PCUK process. Direct alkylation of hydrazines with alkyl halides in the presence of base yields alkyl-substituted hydrazines, but the reaction is typically inefficient due to poor control on level of substitution (same as in ordinary amines). The reduction of hydrazones to hydrazines present a clean way to produce 1,1-dialkylated hydrazines.

In a related reaction, 2-cyanopyridines react with hydrazine to form amide hydrazides, which can be converted using 1,2-diketones into triazines.


Hydrazine is the intermediate in the anaerobic oxidation of ammonia (anammox) process.[49] It is produced by some yeasts and the open ocean bacterium anammox (Brocadia anammoxidans).[50] The false morel produces the poison gyromitrin which is an organic derivative of hydrazine that is converted to monomethylhydrazine by metabolic processes. Even the most popular edible "button" mushroom Agaricus bisporus produces organic hydrazine derivatives, including agaritine, a hydrazine derivative of an amino acid, and gyromitrin.[51][52]


The name "hydrazine" was coined by Emil Fischer in 1875; he was trying to produce organic compounds that consisted of mono-substituted hydrazine.[53] By 1887, Theodor Curtius had produced hydrazine sulfate by treating organic diazides with dilute sulfuric acid; however, he was unable to obtain pure hydrazine, despite repeated efforts.[54][55] [56] Pure anhydrous hydrazine was first prepared by the Dutch chemist Lobry de Bruyn in 1895.[57][58][59]

See also

  • Diazene

  • Hydrazine sulfate

  • List of Stoffs

  • Nitrous oxide fuel blend – Class of liquid rocket propellants

  • USA 193


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