An acid is a molecule or ion capable of donating a hydron (proton or hydrogen ion H+), or, alternatively, capable of forming a covalent bond with an electron pair (a Lewis acid).

The first category of acids is the proton donors or Brønsted acids. In the special case of aqueous solutions, proton donors form the hydronium ion H3O+ and are known as Arrhenius acids. Brønsted and Lowry generalised the Arrhenius theory to include non-aqueous solvents. A Brønsted or Arrhenius acid usually contains a hydrogen atom bonded to a chemical structure that's still energetically favourable after loss of H+.

Aqueous Arrhenius acids have characteristic properties which provide a practical description of an acid. Acids form aqueous solutions with a sour taste, can turn blue litmus red, and react with bases and certain metals (like calcium) to form salts. The word acid is derived from the Latin acidus/acēre meaning sour. An aqueous solution of an acid has a pH less than 7 and is colloquially additionally referred to as 'acid' (as in 'dissolved in acid'), while the strict definition refers only to the solute. A lower pH means a higher acidity, and thus a higher concentration of positive hydrogen ions in the solution. Chemicals or substances having the property of an acid are said to be acidic.

Common aqueous acids include hydrochloric acid (a solution of hydrogen chloride which is found in gastric acid in the stomach and activates digestive enzymes), acetic acid (vinegar is a dilute aqueous solution of this liquid), sulfuric acid (used in car batteries), and citric acid (found in citrus fruits). As these examples show, acids (in the colloquial sense) can be solutions or pure substances, and can be derived from acids (in the strict sense) that are solids, liquids, or gases. Strong acids and a few concentrated weak acids are corrosive, but there are exceptions such as carboranes and boric acid.

The second category of acids are Lewis acids, which form a covalent bond with an electron pair. An example is boron trifluoride (BF3), whose boron atom has a vacant orbital which can form a covalent bond by sharing a lone pair of electrons on an atom in a base, for example the nitrogen atom in ammonia (NH3). Lewis considered this as a generalisation of the Brønsted definition, so that an acid is a chemical species that accepts electron pairs either directly or by releasing protons (H+) into the solution, which then accept electron pairs. Notwithstanding hydrogen chloride, acetic acid, and most additional Brønsted-Lowry acids can't form a covalent bond with an electron pair and are therefore not Lewis acids. Conversely, a large number of Lewis acids aren't Arrhenius or Brønsted-Lowry acids. In modern terminology, an acid is implicitly a Brønsted acid and not a Lewis acid, after chemists almost always refer to a Lewis acid explicitly as a Lewis acid.

## Definitions and concepts

Modern definitions are concerned with the fundamental chemical reactions common to all acids.

Most acids encountered in everyday life are aqueous solutions, or can be dissolved in water, so the Arrhenius and Brønsted-Lowry definitions are the most relevant.

The Brønsted-Lowry definition is the most widely used definition; unless otherwise specified, acid-base reactions are assumed to involve the transfer of a proton (H+) from an acid to a base.

Hydronium ions are acids according to all three definitions. Interestingly, although alcohols and amines can be Brønsted-Lowry acids, they can additionally function as Lewis bases due to the lone pairs of electrons on their oxygen and nitrogen atoms.

### Arrhenius acids

Svante Arrhenius

The Swedish chemist Svante Arrhenius attributed the properties of acidity to hydrogen ions (H+) or protons in 1884. An Arrhenius acid is a substance that, when added to water, increases the concentration of H+ ions in the water. Note that chemists often write H+(aq) and refer to the hydrogen ion when describing acid-base reactions but the free hydrogen nucleus, a proton, doesn't exist alone in water, it exists as the hydronium ion, H3O+. Thus, an Arrhenius acid can additionally be described as a substance that increases the concentration of hydronium ions when added to water. Examples include molecular substances such as HCl and acetic acid.

An Arrhenius base, on the additional hand, is a substance which increases the concentration of hydroxide (OH) ions when dissolved in water. This decreases the concentration of hydronium because the ions react to form H2O molecules:

H3O+(aq) + OH(aq) ⇌ H2O(l) + H2O(l)

Due to this equilibrium, any increase in the concentration of hydronium is accompanied by a decrease in the concentration of hydroxide. Thus, an Arrhenius acid could additionally be said to be one that decreases hydroxide concentration, while an Arrhenius base increases it.

In an acidic solution, the concentration of hydronium ions is greater than 10−7 moles per liter. Since pH is defined as the negative logarithm of the concentration of hydronium ions, acidic solutions thus have a pH of less than 7.

### Brønsted–Lowry acids

Acetic acid, a weak acid, donates a proton (hydrogen ion, highlighted in green) to water in an equilibrium reaction to give the acetate ion and the hydronium ion. Red: oxygen, black: carbon, white: hydrogen.

While the Arrhenius concept is useful for describing a large number of reactions, it is additionally quite limited in its scope. In 1923 chemists Johannes Nicolaus Brønsted and Thomas Martin Lowry independently recognised that acid-base reactions involve the transfer of a proton. A Brønsted-Lowry acid (or simply Brønsted acid) is a species that donates a proton to a Brønsted-Lowry base. Brønsted-Lowry acid-base theory has several advantages over Arrhenius theory. Consider the following reactions of acetic acid (CH3COOH), the organic acid that gives vinegar its characteristic taste:

CH
3
COOH
+ H
2
O
CH
3
COO
+ H
3
O+
CH
3
COOH
+ NH
3
CH
3
COO
+ NH+
4

Both theories easily describe the first reaction: CH3COOH acts as an Arrhenius acid because it acts as a source of H3O+ when dissolved in water, and it acts as a Brønsted acid by donating a proton to water. In the second example CH3COOH undergoes the same transformation, in this case donating a proton to ammonia (NH3), but doesn't relate to the Arrhenius definition of an acid because the reaction doesn't produce hydronium. Nevertheless, CH3COOH is both an Arrhenius and a Brønsted-Lowry acid.

Brønsted-Lowry theory can be used to describe reactions of molecular compounds in nonaqueous solution or the gas phase. Hydrogen chloride (HCl) and ammonia combine under several different conditions to form ammonium chloride, NH4Cl. In aqueous solution HCl behaves as hydrochloric acid and exists as hydronium and chloride ions. The following reactions illustrate the limitations of Arrhenius's definition:

1. H3O+(aq) + Cl(aq) + NH3 → Cl(aq) + NH4+(aq) + H2O
2. HCl(benzene) + NH3(benzene) → NH4Cl(s)
3. HCl(g) + NH3(g) → NH4Cl(s)

As with the acetic acid reactions, both definitions work for the first example, where water is the solvent and hydronium ion is formed by the HCl solute. The next two reactions don't involve the formation of ions but are still proton-transfer reactions. In the second reaction hydrogen chloride and ammonia (dissolved in benzene) react to form solid ammonium chloride in a benzene solvent and in the third gaseous HCl and NH3 combine to form the solid.

### Lewis acids

A third, only marginally related concept was proposed in 1923 by Gilbert N. Lewis, which includes reactions with acid-base characteristics that don't involve a proton transfer. A Lewis acid is a species that accepts a pair of electrons from another species; in additional words, it is an electron pair acceptor. Brønsted acid-base reactions are proton transfer reactions while Lewis acid-base reactions are electron pair transfers. Many Lewis acids aren't Brønsted-Lowry acids. Contrast how the following reactions are described in terms of acid-base chemistry:

In the first reaction a fluoride ion, F, gives up an electron pair to boron trifluoride to form the product tetrafluoroborate. Fluoride "loses" a pair of valence electrons because the electrons shared in the B—F bond are located in the region of space between the two atomic nuclei and are therefore more distant from the fluoride nucleus than they're in the lone fluoride ion. BF3 is a Lewis acid because it accepts the electron pair from fluoride. This reaction can't be described in terms of Brønsted theory because there's no proton transfer. The second reaction can be described using either theory. A proton is transferred from an unspecified Brønsted acid to ammonia, a Brønsted base; alternatively, ammonia acts as a Lewis base and transfers a lone pair of electrons to form a bond with a hydrogen ion. The species that gains the electron pair is the Lewis acid; for example, the oxygen atom in H3O+ gains a pair of electrons when one of the H—O bonds is broken and the electrons shared in the bond become localised on oxygen. Depending on the context, a Lewis acid might additionally be described as an oxidizer or an electrophile. Organic Brønsted acids, such as acetic, citric, or oxalic acid, aren't Lewis acids. They dissociate in water to produce a Lewis acid, H+, but at the same time additionally yield an equal amount of a Lewis base (acetate, citrate, or oxalate, respectively, for the acids mentioned). Few, if any, of the acids discussed in the following are Lewis acids.

## Dissociation and equilibrium

Reactions of acids are often generalised in the form HA ⇌ H+ + A, where HA represents the acid and A is the conjugate base. This reaction is referred to as protolysis. The protonated form (HA) of an acid is additionally at times referred to as the free acid.

Acid-base conjugate pairs differ by one proton, and can be interconverted by the addition or removal of a proton (protonation and deprotonation, respectively). Note that the acid can be the charged species and the conjugate base can be neutral in which case the generalised reaction scheme can be written as HA+ ⇌ H+ + A. In solution there exists an equilibrium between the acid and its conjugate base. The equilibrium constant K is an expression of the equilibrium concentrations of the molecules or the ions in solution. Brackets indicate concentration, such that [H2O] means the concentration of H2O. The acid dissociation constant Ka is generally used in the context of acid-base reactions. The numerical value of Ka is equal to the product of the concentrations of the products divided by the concentration of the reactants, where the reactant is the acid (HA) and the products are the conjugate base and H+.

${displaystyle K_{a}={frac {ce {[H+][A^{-}]}}{ce {[HA]}}}}$

The stronger of two acids will have a higher Ka than the weaker acid; the ratio of hydrogen ions to acid will be higher for the stronger acid as the stronger acid has a greater tendency to lose its proton. Because the range of possible values for Ka spans a large number of orders of magnitude, a more manageable constant, pKa is more frequently used, where pKa = −log10 Ka. Stronger acids have a smaller pKa than weaker acids. Experimentally determined pKa at 25 °C in aqueous solution are often quoted in textbooks and reference material.

## Nomenclature

In the classical naming system, acids are named according to their anions. That ionic suffix is dropped and replaced with a new suffix (and at times prefix), according to the table below. For example, HCl has chloride as its anion, so the -ide suffix makes it take the form hydrochloric acid. In the IUPAC naming system, "aqueous" is simply added to the name of the ionic compound. Thus, for hydrogen chloride, the IUPAC name would be aqueous hydrogen chloride. The prefix "hydro-" is added only if the acid is made up of just hydrogen and one additional element.

Classical naming system:

Anion prefixAnion suffixAcid prefixAcid suffixExample
perateperic acidperchloric acid (HClO4)
ateic acidchloric acid (HClO3)
iteous acidchlorous acid (HClO2)
hypoitehypoous acidhypochlorous acid (HClO)
idehydroic acidhydrochloric acid (HCl)

## Acid strength

The strength of an acid refers to its ability or tendency to lose a proton. A strong acid is one that completely dissociates in water; in additional words, one mole of a strong acid HA dissolves in water yielding one mole of H+ and one mole of the conjugate base, A, and none of the protonated acid HA. In contrast, a weak acid only partially dissociates and at equilibrium both the acid and the conjugate base are in solution. Examples of strong acids are hydrochloric acid (HCl), hydroiodic acid (HI), hydrobromic acid (HBr), perchloric acid (HClO4), nitric acid (HNO3) and sulfuric acid (H2SO4). In water each of these essentially ionises 100%. The stronger an acid is, the more easily it loses a proton, H+. Two key factors that contribute to the ease of deprotonation are the polarity of the H—A bond and the size of atom A, which determines the strength of the H—A bond. Acid strengths are additionally often discussed in terms of the stability of the conjugate base.

Stronger acids have a larger Ka and a more negative pKa than weaker acids.

Sulfonic acids, which are organic oxyacids, are a class of strong acids. A common example is toluenesulfonic acid (tosylic acid). Unlike sulfuric acid itself, sulfonic acids can be solids. In fact, polystyrene functionalized into polystyrene sulfonate is a solid strongly acidic plastic that's filterable.

Superacids are acids stronger than one hundred percent sulfuric acid. Examples of superacids are fluoroantimonic acid, magic acid and perchloric acid. Superacids can permanently protonate water to give ionic, crystalline hydronium "salts". They can additionally quantitatively stabilise carbocations.

While Ka measures the strength of an acid compound, the strength of an aqueous acid solution is measured by pH, which is an indication of the concentration of hydronium in the solution. The pH of a simple solution of an acid compound in water is determined by the dilution of the compound and the compound's Ka.

## Chemical characteristics

### Monoprotic acids

Monoprotic acids are those acids that are able to donate one proton per molecule throughout the process of dissociation (sometimes called ionization) as shown below (symbolized by HA):

HA(aq) + H2O(l) ⇌ H3O+(aq) + A(aq)         Ka

Common examples of monoprotic acids in mineral acids include hydrochloric acid (HCl) and nitric acid (HNO3). On the additional hand, for organic acids the term mainly indicates the presence of one carboxylic acid group and at times these acids are known as monocarboxylic acid. Examples in organic acids include formic acid (HCOOH), acetic acid (CH3COOH) and benzoic acid (C6H5COOH).

### Polyprotic acids

Polyprotic acids, additionally known as polybasic acids, are able to donate more than one proton per acid molecule, in contrast to monoprotic acids that only donate one proton per molecule. Specific types of polyprotic acids have more specific names, such as diprotic acid (two potential protons to donate) and triprotic acid (three potential protons to donate).

A diprotic acid (here symbolised by H2A) can undergo one or two dissociations depending on the pH. Each dissociation has its own dissociation constant, Ka1 and Ka2.

H2A(aq) + H2O(l) ⇌ H3O+(aq) + HA(aq)       Ka1
HA(aq) + H2O(l) ⇌ H3O+(aq) + A2−(aq)       Ka2

The first dissociation constant is typically greater than the second; i.e., Ka1 > Ka2. For example, sulfuric acid (H2SO4) can donate one proton to form the bisulfate anion (HSO4), for which Ka1 is quite large; then it can donate a second proton to form the sulfate anion (SO42−), wherein the Ka2 is intermediate strength. The large Ka1 for the first dissociation makes sulfuric a strong acid. In a similar manner, the weak unstable carbonic acid (H2CO3) can lose one proton to form bicarbonate anion (HCO3) and lose a second to form carbonate anion (CO32−). Both Ka values are small, but Ka1 > Ka2 .

A triprotic acid (H3A) can undergo one, two, or three dissociations and has three dissociation constants, where Ka1 > Ka2 > Ka3.

H3A(aq) + H2O(l) ⇌ H3O+(aq) + H2A(aq)         Ka1
H2A(aq) + H2O(l) ⇌ H3O+(aq) + HA2−(aq)       Ka2
HA2−(aq) + H2O(l) ⇌ H3O+(aq) + A3−(aq)         Ka3

An inorganic example of a triprotic acid is orthophosphoric acid (H3PO4), usually just called phosphoric acid. All three protons can be successively lost to yield H2PO4, then HPO42−, and finally PO43−, the orthophosphate ion, usually just called phosphate. Even though the positions of the three protons on the original phosphoric acid molecule are equivalent, the successive Ka values differ after it is energetically less favourable to lose a proton if the conjugate base is more negatively charged. An organic example of a triprotic acid is citric acid, which can successively lose three protons to finally form the citrate ion.

Although the subsequent loss of each hydrogen ion is less favorable, all of the conjugate bases are present in solution. The fractional concentration, α (alpha), for each species can be calculated. For example, a generic diprotic acid will generate 3 species in solution: H2A, HA, and A2−. The fractional concentrations can be calculated as below when given either the pH (which can be converted to the [H+]) or the concentrations of the acid with all its conjugate bases:

{displaystyle {begin{aligned}alpha _{ce {H2A}}&={frac {ce {[H+]^{2}}}{{ce {[H+]^{2}}}+[{ce {H+}}]K_{1}+K_{1}K_{2}}}={frac {ce {[H2A]}}{ce {{[H2A]}+{[HA^{-}]}+{[A^{2-}]}}}}alpha _{ce {HA^{-}}}&={frac {[{ce {H+}}]K_{1}}{{ce {[H+]^{2}}}+[{ce {H+}}]K_{1}+K_{1}K_{2}}}={frac {ce {[HA^{-}]}}{ce {{[H2A]}+{[HA^{-}]}+{[A^{2-}]}}}}alpha _{ce {A^{2-}}}&={frac {K_{1}K_{2}}{{ce {[H+]^{2}}}+[{ce {H+}}]K_{1}+K_{1}K_{2}}}={frac {ce {[A^{2-}]}}{ce {{[H2A]}+{[HA^{-}]}+{[A^{2-}]}}}}end{aligned}}}

A plot of these fractional concentrations against pH, for given K1 and K2, is known as a Bjerrum plot. A pattern is observed in the above equations and can be expanded to the general n -protic acid that has been deprotonated i -times:

${displaystyle alpha _{{ce {H}}_{n-i}A^{i-}}={{[{ce {H+}}]^{n-i}displaystyle prod _{j=0}^{i}K_{j}} over {displaystyle sum _{i=0}^{n}{Big [}[{ce {H+}}]^{n-i}displaystyle prod _{j=0}^{i}K_{j}}{Big ]}}}$

where K0 = 1 and the additional K-terms are the dissociation constants for the acid.

### Neutralization

Hydrochloric acid (in beaker) reacting with ammonia fumes to produce ammonium chloride (white smoke).

Neutralization is the reaction between an acid and a base, producing a salt and neutralised base; for example, hydrochloric acid and sodium hydroxide form sodium chloride and water:

HCl(aq) + NaOH(aq) → H2O(l) + NaCl(aq)

Neutralization is the basis of titration, where a pH indicator shows equivalence point when the equivalent number of moles of a base have been added to an acid. It is often wrongly assumed that neutralisation should result in a solution with pH 7.0, which is only the case with similar acid and base strengths throughout a reaction.

Neutralization with a base weaker than the acid results in a weakly acidic salt. An example is the weakly acidic ammonium chloride, which is produced from the strong acid hydrogen chloride and the weak base ammonia. Conversely, neutralising a weak acid with a strong base gives a weakly basic salt, e.g. sodium fluoride from hydrogen fluoride and sodium hydroxide.

### Weak acid–weak base equilibrium

In order for a protonated acid to lose a proton, the pH of the system must rise above the pKa of the acid. The decreased concentration of H+ in that basic solution shifts the equilibrium towards the conjugate base form (the deprotonated form of the acid). In lower-pH (more acidic) solutions, there's a high enough H+ concentration in the solution to cause the acid to remain in its protonated form.

Solutions of weak acids and salts of their conjugate bases form buffer solutions.

## Applications of acids

There are numerous uses for acids. Acids are often used to remove rust and additional corrosion from metals in a process known as pickling. They might be used as an electrolyte in a wet cell battery, such as sulfuric acid in a car battery.

Strong acids, sulfuric acid in particular, are widely used in mineral processing. For example, phosphate minerals react with sulfuric acid to produce phosphoric acid for the production of phosphate fertilizers, and zinc is produced by dissolving zinc oxide into sulfuric acid, purifying the solution and electrowinning.

In the chemical industry, acids react in neutralisation reactions to produce salts. For example, nitric acid reacts with ammonia to produce ammonium nitrate, a fertilizer. Additionally, carboxylic acids can be esterified with alcohols, to produce esters.

Acids are used as additives to drinks and foods, as they alter their taste and serve as preservatives. Phosphoric acid, for example, is a component of cola drinks. Acetic acid is used in day-to-day life as vinegar. Carbonic acid is an important part of a few cola drinks and soda. Citric acid is used as a preservative in sauces and pickles.

Tartaric acid is an important component of a few commonly used foods like unripened mangoes and tamarind. Natural fruits and vegetables additionally contain acids. Citric acid is present in oranges, lemon and additional citrus fruits. Oxalic acid is present in tomatoes, spinach, and especially in carambola and rhubarb; rhubarb leaves and unripe carambolas are toxic because of high concentrations of oxalic acid.

Ascorbic acid (Vitamin C) is an essential vitamin for the human body and is present in such foods as amla (Indian gooseberry), lemon, citrus fruits, and guava.

Certain acids are used as drugs. Acetylsalicylic acid (Aspirin) is used as a pain killer and for bringing down fevers.

Acids play important roles in the human body. The hydrochloric acid present in the stomach aids in digestion by breaking down large and complex food molecules. Amino acids are required for synthesis of proteins required for growth and repair of body tissues. Fatty acids are additionally required for growth and repair of body tissues. Nucleic acids are important for the manufacturing of DNA and RNA and transmitting of traits to offspring through genes. Carbonic acid is important for maintenance of pH equilibrium in the body.

### Acid catalysis

Acids are used as catalysts in industrial and organic chemistry; for example, sulfuric acid is used in quite large quantities in the alkylation process to produce gasoline. Strong acids, such as sulfuric, phosphoric and hydrochloric acids additionally effect dehydration and condensation reactions. In biochemistry, a large number of enzymes employ acid catalysis.

## Biological occurrence

Basic structure of an amino acid.

Many biologically important molecules are acids. Nucleic acids, which contain acidic phosphate groups, include DNA and RNA. Nucleic acids contain the genetic code that determines a large number of of an organism's characteristics, and is passed from parents to offspring. DNA contains the chemical blueprint for the synthesis of proteins which are made up of amino acid subunits. Cell membranes contain fatty acid esters such as phospholipids.

An α-amino acid has a central carbon (the α or alpha carbon) which is covalently bonded to a carboxyl group (thus they're carboxylic acids), an amino group, a hydrogen atom and a variable group. The variable group, additionally called the R group or side chain, determines the identity and a large number of of the properties of a specific amino acid. In glycine, the simplest amino acid, the R group is a hydrogen atom, but in all additional amino acids it is contains one or more carbon atoms bonded to hydrogens, and might contain additional elements such as sulfur, oxygen or nitrogen. With the exception of glycine, naturally occurring amino acids are chiral and almost invariably occur in the L-configuration. Peptidoglycan, found in a few bacterial cell walls contains a few D-amino acids. At physiological pH, typically around 7, free amino acids exist in a charged form, where the acidic carboxyl group (-COOH) loses a proton (-COO) and the basic amine group (-NH2) gains a proton (-NH3+). The entire molecule has a net neutral charge and is a zwitterion, with the exception of amino acids with basic or acidic side chains. Aspartic acid, for example, possesses one protonated amine and two deprotonated carboxyl groups, for a net charge of −1 at physiological pH.

Fatty acids and fatty acid derivatives are another group of carboxylic acids that play a significant role in biology. These contain long hydrocarbon chains and a carboxylic acid group on one end. The cell membrane of nearly all organisms is primarily made up of a phospholipid bilayer, a micelle of hydrophobic fatty acid esters with polar, hydrophilic phosphate "head" groups. Membranes contain additional components, a few of which can participate in acid-base reactions.

In humans and a large number of additional animals, hydrochloric acid is a part of the gastric acid secreted within the stomach to help hydrolyze proteins and polysaccharides, as well as converting the inactive pro-enzyme, pepsinogen into the enzyme, pepsin. Some organisms produce acids for defense; for example, ants produce formic acid.

Acid-base equilibrium plays a critical role in regulating mammalian breathing. Oxygen gas (O2) drives cellular respiration, the process by which animals release the chemical potential energy stored in food, producing carbon dioxide (CO2) as a byproduct. Oxygen and carbon dioxide are exchanged in the lungs, and the body responds to changing energy demands by adjusting the rate of ventilation. For example, throughout periods of exertion the body rapidly breaks down stored carbohydrates and fat, releasing CO2 into the blood stream. In aqueous solutions such as blood CO2 exists in equilibrium with carbonic acid and bicarbonate ion.

CO2 + H2O ⇌ H2CO3 ⇌ H+ + HCO3

It is the decrease in pH that signals the brain to breathe faster and deeper, expelling the excess CO2 and resupplying the cells with O2.

Aspirin (acetylsalicylic acid) is a carboxylic acid.

Cell membranes are generally impermeable to charged or large, polar molecules because of the lipophilic fatty acyl chains comprising their interior. Many biologically important molecules, including a number of pharmaceutical agents, are organic weak acids which can cross the membrane in their protonated, uncharged form but not in their charged form (i.e. as the conjugate base). For this reason the activity of a large number of drugs can be enhanced or inhibited by the use of antacids or acidic foods. The charged form, however, is often more soluble in blood and cytosol, both aqueous environments. When the extracellular environment is more acidic than the neutral pH within the cell, certain acids will exist in their neutral form and will be membrane soluble, allowing them to cross the phospholipid bilayer. Acids that lose a proton at the intracellular pH will exist in their soluble, charged form and are thus able to diffuse through the cytosol to their target. Ibuprofen, aspirin and penicillin are examples of drugs that are weak acids.

## Common acids

### Sulfonic acids

A sulfonic acid has the general formula RS(=O)2–OH, where R is an organic radical.

### Carboxylic acids

A carboxylic acid has the general formula R-C(O)OH, where R is an organic radical. The carboxyl group -C(O)OH contains a carbonyl group, C=O, and a hydroxyl group, O-H.

### Halogenated carboxylic acids

Halogenation at alpha position increases acid strength, so that the following acids are all stronger than acetic acid.

### Vinylogous carboxylic acids

Normal carboxylic acids are the direct union of a carbonyl group and a hydroxyl group. In vinylogous carboxylic acids, a carbon-carbon double bond separates the carbonyl and hydroxyl groups.